![]() There were more than enough opportunities for him to elaborate on the reasons. Since he's still just a kid, him deciding to run from home has got to be up there in terms of major events that likely form part of who he is today (at the time of the movie), so knowing that helps us understand where he's coming from. The movie doesn't tell us whatsoever, and sometimes leaving that blank can be effective, but I don't think it was in this case. He could have just been bored or dissatisfied. ![]() His parents could have been genuinely abusive, absent or just strict. I don't deny that Hodaka's home life was unhappy, but it could have been anything. She was just sick of the monotony and the expectations set on her. Mitsuha in Your Name felt the same about her town and aside from some tension with her father, her life wasn't all that bad. I think a lot of people have entertained that fantasy at least once in their life. Casting aside your boring old life for a fresh start in a new place is exciting on paper at least. Maybe not as extreme but other people's lives are going to be fucked.Įscaping from a small town he lived in (on a remote island, nonetheless) to a big city, especially one as cool as Tokyo, is an attractive idea for a lot of young people. It would be like Taki causing the meteor strike to save Mitsuha, or at the very least not stopping it in exchange for her life. And we do care because we like Hina, but when the entire city (and probably a lot of the country) is going to be permanently changed, it's a bit harder to get on board with. Your Name's stakes are so much more real - in WWY, the thing Hodaka wants to save is Hina's life, which is all well and good, but that's all the movie wants us to care about. Since he returns to his home at the end and little else is said (and he's then able to go back to Tokyo on his own) we can assume that his home life probably isn't that bad. If he his a victim of abuse, then okay, we know why he'd run away. It's hard to root for him when we don't really know what set him on this path. All we're told is that he "feels suffocated" at home, but that could be anything from him being abused to him just being a whiny brat. Not everything needs to be explained, but we don't really know enough about Hodaka to really understand him. The fact that we barely get any insight into the characters' backstories hurts it as well, I think. What about all the people's homes they just destroyed? What's romantic about being self-centered pieces of shit? It sucks that they were put in that situation, but it's hard to have any sympathy for them when they don't then address the consequences of their actions. In WWY, they just don't give a shit about sacrificing an entire city just for the sake of a teen romance. That's romantic in a deep and meaningful way. Whether or not they were in love, they did the right thing for the right reason and supported each other through it. They don't need to save everyone, but they do because they both care about the town, even when Mitsuha is sick of it. In Your Name, the characters work together to help each other with the things that are more important than either of them. ![]() I just can't get behind WWY for the final act and story direction. I watched them back to back in the cinema and whilst they are both mind blowingly pretty, Your Name has a significantly better story.
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That makes the boot extend out proportionally more than I’m used to, and coupled with that defiantly reinforced toe, I just can’t quite fall totally in love. Also (and we’ll get into this in the next section), I think these fit me about a half to maybe even a full size big compared to my two cherished pairs of Iron Rangers. That famous toe is part of what irks me at times-it’s VERY structured, and I wish it would just give up a bit of its pride and sag and drape and just be less rigid about the way it’s living its life. The boots, despite working the streets for five months, aren’t necessarily worn in yet in a true sense Red Wing magic takes some marination. The other mind says: now that I’m wearing these boots and looking down at them, they look…different than I expected. They’re an icon for a reason and display a clean, in some ways perfect design. One mind says: they look amazing sitting on my shoe rack, they look amazing in photos, they look amazing on other people I see wearing them on the streets. I’m going to come right out and say it: I’m two minds about these boots in terms of how they look. While things started with Red Wing’s taller, 8-inch 877 model, the introduction of the 6-inch 875 Moc Toe boot also presaged Red Wing’s eventual launch of a specific Heritage line, and the company’s focus on creating more lifestyle-ready footwear, in addition to their well-loved true work boots. Initially adopted by farmers who found the wedge outsoles provided traction in the fields without picking up too much dirt and gunk throughout the day, and the Goodyear welt construction to be appropriately waterproof, Red Wing Moc Toes eventually became must-wear boots for factory workers, contractors, sportsmen (Red Wing’s Irish Setter line especially focused on them), and eventually…everybody. The “Moc,” perhaps obviously and perhaps not, comes from “moccasin.” The original Red Wing Moc Toes, which were introduced in the 50’s, were inspired by Native American footwear, specifically in their now-iconic toe design (even though the way the footwear are built is very different- see this interview with Quoddy’s CEO to learn a lot more about true moccasin construction). How I Cared for Them: Cedar shoe trees occasionally inserted when not being worn wiped clean whenever dirty brushed periodically one treatment of Armstrong’s All Natural leather conditioner around 4 monthsĪ Bit of History on Red Wing Moc Toe Boots Worn How Often?: On average, once a week for those five months Price: $279 (full disclosure: this pair was sent to me by Red Wing specifically for this review, with the knowledge that it would be a fully honest and editorial evaluation of the boots) Model: 6-inch Classic Moc Toe in Briar Oil Slick leather, model 8138 White’s Boots Review: My Smokejumpers, Oxfords, and MTO 350s.Paraboot Avignon: A Wildly Comfortable, Personality-Filled Split-Toe.A Deep Look at Heinrich Dinkelacker’s Signature Buda Brogue.Tricker’s Stow: A Two-Year Review of a Very Excellent Country Boot.Red Wing Iron Ranger: A Four-Year Review of a Timeless Boot.Tricker’s x Division Road Bourton: Five Months Deep Into Some Wonderful Kudu.Thorogood Moc-Toe Boot In Tobacco Leather: Five-Year Review.Onderhoud Handmade: Possibly the Best Value in Hand-Welted Boots.Alden Indy 403C Review: A Three-Year Look at a Near-Perfect Boot. ![]() ![]() ![]()
![]() This one-to-one ratio of charges is not, however, the most common state for many elements. The overall charge on the atom is zero, because the magnitude of the negative charge is the same as the magnitude of the positive charge. The electrovalent bond between ions results from the electrostatic attraction of opposite charges.\) and hypochlorite is ClO −. This is because the number of electrons (negative in charge) is equal to the number of protons (positive in charge).After fluorine gains the electron from sodium, it becomes a negative ion (9 p + 10 e- = -1).After sodium losses the electron, it becomes a positive ion (11 p + 10 e- = +1).Fluorine gains one electron to possess an octet. Here, Na loses one electron to possess an octet. Determine the numbers of electrons that the atoms will lose and gain by the Octet Rule.Solution: Stepwise formulation of the compound is as follows, Q 1] Determine the formula of a compound formed by the reaction of sodium and fluoride. Solved Examples for Ionic Compound Formula Each ion becomes surrounded by solvent molecules.Įlemental atoms generally lose, gain, or share electrons with other atoms so as to attain an equivalent electron structure because of the nearest rare gas with eight electrons within the outer level. For an ionic compound to dissolve, the electrostatic bonds holding the ions in their rigid space lattice must get replaced by attractions between ions and solvent molecules. ![]() In an ionic compound, like common salt, NaCl, or magnesia MgO, the formula tells us the right ratio of elements present, but it doesn’t specify the unit. Polyatomic ions may be either positive or negative, for example: NH 4 + (ammonium) cation SO 4 2 - (sulfate) anion The principles of ionic bonding with polyatomic ions are the same as those with monatomic ions. An ion ( / a.n, - n /) 1 is an atom or molecule with a net electrical charge. The group of atoms as a whole acts as a charged species in forming an ionic compound with an oppositely charged ion. Forming an ionic bond, Li and F become Li + and F ions. The sum of the charges of the positive ions (cations) must always equal to sum of the. There’s always a minimum of a little degree of covalent bonding character in ionic compounds. Electron transfer between lithium (Li) and fluorine (F). Ionic compounds always contain a positive ion and a negative ion.2. However, absolutely pure ionic bonding doesn’t exist. This is often different from covalent bonding, during which electrons are shared by atoms, forming directional bonds. It is often an easy positive-negative Coulombic attraction between point charges. Source: Ionic bonding isn’t directional in its purest form. If the ionic compound is soluble during a solvent, we get as a solid compound by evaporation of solid solvent from this electrolyte solution. And, therefore, the process are often thermodynamically understood using the Born–Haber cycle. In some reactions between highly reactive metals (usually from Group 1 or Group 2) and highly electronegative halogen gases, or water, the atoms are often ionized by electron transfer. Ionic compounds without these ions also are referred to as salts and may be formed by acid-base reactions. And people containing basic ions hydroxide (OH−) or oxide (O2−) are bases. Ionic compounds containing hydrogen ions (H+) are acids. It also can include the electron transfer reaction of reactive metals with reactive non-metals, like halogen gases. ![]() ![]() Production of ionic compounds is often from their constituent ions with the assistance of evaporation of their solvent, precipitation, freezing, a solid-state reaction. Ionic compounds are insoluble or have very low solubility in non-polar solvents. they’re nearly always electrically insulating as they’re solids. Ionic compounds have high melting and boiling points.
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There are a number of file compressor tools available with varied features and functions. 5.25 11 Ways to Compress Videos Free Online.4.5 Compress Video for Facebook, Instagram.3.10 HandBrake Video Compressor AlternativeĤ.3.5 Compress Videos with Windows Media Player Alternatives.3.3 Make Windows Movie Maker Resize Video.2.10 Top 8 Video Size Reducers for Android.2.9 10 Video Compressor App Android/iPhone.2.7 MMS Video Size Limit for iPhone/Android.Compress Video/Audio in Different Formats + Also, our unmanned system purges all data after one hour, so you don’t need to worry about the security of your data.Īll uploaded data is deleted after 1 hour.Compress Videos 1. Your original files will stay untouched on your system, so if you are unhappy with your compressed files, you can simply try again. There is no need to be worried about the safety of our free service. You can use this tool as many times as needed without cost. Ready for another batch? Hit the “CLEAR QUEUE” button and start again. If you don’t need all of them, you can hit the “DOWNLOAD” button under each thumbnail instead to grab each one individually. ![]() This will download a ZIP file with all your compressed images. When you are satisfied with the current batch, hit the “DOWNLOAD ALL” button. When you’re finished, hit the “APPLY” button and move on to repeat these steps with the next image. Now, move the quality slider up or down until you settle on a file size/quality setting you think is just right. Tap the thumbnail of the image you’d like to tweak. However, if you want more or less compression, you can control it. You’ll be able to see their real-time progress as our server analyzes them.Īs stated, our server will determine the ideal compression rate to reduce the file size while not reducing quality too much. Once uploaded, you’ll see thumbnails for all your images arriving in the queue. Our server can automatically parse out the files for you.įirst, hit the “Upload Files” button and navigate to your images. In other words, you don’t need to only upload JPGs and wait to upload PNGs. You can upload up to 20 images at once and you can feel free to mix and match file types. To begin, you’ll need to upload some images you’d like to compress. This system intelligently analyzes uploaded images and reduces them to the smallest possible file size without negatively affecting the overall quality. It supports three file types: PNG, JPG/JPEG, and GIF. Our tool uses lossy compression to shrink down image files. Compressing them could free up more internal storage, fixing this problem. These images could be taking up a lot of hard drive space and preventing you from taking more photos. Likewise, you might have large images on your phone. Compressing this image would be very useful. Depending on your needs, this could be too big. A JPG from a professional DSLR camera, for example, could be dozens of megabytes. Why would you want to compress images?ĭepending on the source of an image, the file could be quite large. With lossy compression, how small you want the final file to be will depend on how much loss of quality you’re comfortable with. ![]() This results in a smaller file but with a reduced quality. Lossy compression is when the compressor removes excessive or unimportant bits from the original file. This results in a smaller file that has the exact same quality as the original. Lossless compression is when the compression tool removes empty, needless, or duplicated bits from the original file. There are two types of compression: lossless and lossy. Simply put, it means converting a large file into a smaller file. In terms of digital files, compression is the act of encoding information using fewer bits than what’s found in the original file. ![]() Time to start pack-a-lackin’ – we leave for Atlanta TOMORROW and our plane for the Bahamas leaves on Tuesday. Happy Mother’s Day to all of the madres out there □ Our application has more than 40 Happy Mothers Day Share with whom else do you want pretty pictures Happy Mothers Day Download this application right now. Pretty ahhhhmazing □ I’m off to start the vacation pack-stravaganza but wanted to say ¡Feliz Día de las Madres Esta canción es para ellas. :: Le envío mis mejores deseos y abrazos. Download royalty-free stock photos, vectors, HD footage and more on Adobe Stock. ![]() Categoria: Frases ¡Feliz Día de la Madre para mi suegra. Search from thousands of royalty-free Feliz Dia De La Madre stock images and video for your next project. ![]() :: En este Día de la Madre, le agradezco por todo el amor y la amabilidad que ha mostrado hacia mí desde que llegué a la familia. Mam, el mejor regalo que te puedo dar es todo mi amor, cario y comprensin, el mismo regalo que me has hecho t desde que llegu a este mundo. Categoria: Frases ¡Feliz Día de la Madre para mi suegra. I started my Sunday off with some glorious perfect protein pancakes (1.5x the mix) with vegan chocolate chips, strawberries and banana Hoy es un día muy especial para todas las mamás. Feliz Da de la Madre, gracias por estar ah, por quererme, por cuidarme y por hacerme tan feliz. Si deseas compartir con mam algn lindo mensaje o. Este 2022, la festividad cae este 8 de mayo. We chillaxed and I watched Jude Law The Holiday while the pilot read and we called it a night. Como cada ao, en Estados Unidos se celebra el Da de la Madre el segundo domingo de mayo. I’d been waiting for the pilot to get home to share that piece of salmon with me- it was ginormous and I don’t like leftover fish. Feliz Dia das Mães Día de la Madre, Cristo Rey, Día de St Andrews, Día de San Nicolás, Noche de Vigilancia, Thaipusam, Tu Bishvat png. ¡Feliz día de las mamás Below are some short common phrases that you can use to wish your mother a Happy Mother’s Day in Spanish as well as the English translation. The pilot and I had a pretty chill night last night- we went to Wizzle searching for travel cups (apparently you can bring your own cups to use at the resort if ya want to be eco-friendly, like me, or if you want larger drinks… like the pilot) and had Asian-inspired feast for dinnerīrown So Fly Fried Rice with water chestnuts, egg and veggiesĪnd wild-caught salmon marinated in Nama shoyu, garlic, ginger, cayenne, rice wine vinegar and honey With bright colors, floral prints, and bold letters, this is the perfect spring-y design to celebrate Mothers Day. Celebrate your Mother, or any special woman in your life who youd like to wish a Happy Mothers Day, with a Feliz Dia de Las Madres musical Mothers Day. ![]() No portion of this site may be reproduced without the express written permission of the Las Vegas Raiders.Hi guys! Hope you’re having a very happy Sunday! Sorprende a una Mam especial este Da de las Madres con una tarjeta de felicitacin personalizada enviada a donde est. The Known World professed by Cook is largely depicted in the Expert Set adventures and in B6: "The Veiled Society" (1984). This inclusion would kick off the Cook era of the Known World (1981-1986), when it was still a pretty wild and unpopulated place, before the Gazetteers filled it in more (and dramatically increased the population). The rulebook contains a one-page describing the Grand Duchy of Karameikos (along with some of its inhabitants) followed by a single-page hex map. The Expert Rulebook's other historical first was its introduction of the Known World of Mystara. AD&D's biggest push into the area, the Wilderness Survival Guide (1986), was never nearly as successful as Expert D&D's wilderness exploration.Įxpanding the 'Known World'. In the mid-80s, wilderness adventures occasionally snuck into other game lines - including adventures like the Basic Set module B8: "Journey to the Rock" (1984) and AD&D's N2: "The Forest Oracle" (1984) - but those adventures tended to be constrained railroads rather than the wide-open hex crawls of some Expert modules. The Expert-level adventures would all be largely wilderness focused, highlighting a category of adventure that wasn't seen before or afterward - at least not at the same level. ![]() The resulting "hex crawls" would be very different from the "dungeon crawls" that D&D was built on. The Expert Rulebook went against all of these early expectations by saying bluntly, "Adventures will take place outside the dungeon." It goes on to provide tips for conducting a wilderness campaign and specific rules for wilderness travel of different sorts. Moldvay's Basic Set didn't just keep with that dungeon-delving trend, but offered it up as the norm, saying in its introduction, "At the start of the game, the players enter the dungeon…" The only real exception was the eponymous T1: "Village of Hommlet" (1979), and that was a far cry from the wilderness hex exploration suggested in original D&D. The original D&D divided adventuring between "the underworld" and "the wilderness," but prior to the release of the Expert Set, almost all published D&D adventures focused on dungeons, caverns, ruins, and monstrous lairs. Though halflings, elves, and dwarves are limited to 8, 10, and 12 levels, respectively, that's not necessarily a big deal when the game only went up to level 14.Įnter the Wilderness. However, they make a lot more sense in the "B/X" presentation. ![]() Levels limits for demihumans were a point of contention in both Basic D&D and AD&D. Instead, that desire would have to await the Frank Mentzer revision of Basic D&D, which began in 1983.Ībout Those Level Limits. Gygax had also planned for a "D&D Companion Set," which would carry Basic D&D characters from levels 15-36, but that would not appear under the Moldvay/Zeb "B/X" edition of Basic D&D. When Gary Gygax first announced the upcoming Expert Rules in The Dragon #35 (March 1980), he said they would include "new classes, spells, magic, monsters, and so on." There were indeed magic item, monsters, and spells, but sadly no new classes. Ironically, this controversy caused sales of Holmes' Basic Set to soar and resulted in a new directive for the newly created Design Department at TSR: supplement Basic D&D (which only covered levels 1-3) with Expert Rules that would allow players to play "through at least 12th level of experience." After that, TSR didn't put any more work into the Basic D&D game, instead focusing on AD&D (1977-1979).Įnter the "James Dallas Egbert III affair" (1979), where a college student disappeared and D&D somehow took the blame in the media. ![]() Eric Holmes simplifying the original D&D rules (1974) as the first Dungeons & Dragons Basic Set (1977). For the first time ever, it offered the opportunity to achieve levels 4-14 in TSR's introductory game.īeyond Basic. The Dungeons & Dragons Expert Rules (1981), by David "Zeb" Cook, was released simultaneously with the second edition Basic Rules (1981) in January 1981. This is the 1981 edition of the D&D Expert Rulebook by Dave Cook, which was sold as a counterpart to the Moldvay D&D Basic Set. Research in the Storage Complex Feasibility projects focuses on one or more specific reservoirs within the defined storage complex, encompassing: Six CarbonSAFE Storage Complex Feasibility projects performed work under Phase II. The progress made by the CarbonSAFE Initiative will instill greater confidence that commercial-scale CCS projects can be integrated in a technically and economically feasible manner. Project research will provide insight into the integration of site characterization information into reservoir simulations and design of injection and monitoring strategies. The CarbonSAFE effort contributes to furthering the development and refinement of technologies and techniques critical to the characterization of potential 50+ million metric ton (MMT) storage complexes. Results will improve the understanding of project screening, site selection, characterization, baseline monitoring, verification, and accounting (MVA) procedures, and information necessary to submit appropriate permit applications for such projects. The vision of CarbonSAFE is to understand the development of a CCS storage complex from the feasibility study until the point of injection through the following phases of project progress: Integrated Carbon Capture and Storage Pre-Feasibility, Storage Complex Feasibility, Site Characterization and Permitting, and Construction.The CarbonSAFE Initiative will reduce technical risk, uncertainty, and the cost of commercial-scale saline storage projects. ![]() Building upon the knowledge and experience of the Regional Carbon Sequestration Partnerships’ (RCSPs’) efforts, this initiative is performing identification and detailed characterization of geologic storage sites. The Carbon Storage Assurance Facility Enterprise (CarbonSAFE) Initiative began in 2016 with the goal of addressing the key gaps on the critical path towards Carbon Capture and Storage (CCS) deployment.
![]() Denatured alcohol burns very cleanly, more so than other fuels. One very common use of denatured alcohol is by using it as an efficient fuel for oil heaters such as camping stoves. Use denatured alcohol on an old cloth to wipe away any excess sawdust that may still be present after sanding. Professional carpenters often mix shellac with denatured alcohol to effectively protect the wood from scratches and to give it a good finish.ĭenatured alcohol also works well with sanding wood. Try it out, and you might be surprised how effective it is. Denatured alcohol can be used for general house cleaning General House Cleaningĭilute denatured alcohol with warm water (50%) and you can pretty much clean and sanitize your whole house, especially bathrooms, kitchens, sinks, and toilets. Make sure you properly dry the area after wiping it clean. Let it soak in for a few minutes and then wipe it off with a clean, damped rag. Use a sprayer to spray the patches of mold with denatured alcohol. Mold can be very harmful to our health so it’s important to avoid or remove it. Methylated Spirits is a denatured alcohol and a very versatile industrial cleaning agent, commonly used as a hard surface cleaner. Once it’s there, it’s very difficult to get rid of it permanently. Especially isopropyl rubbing alcohol because this type of alcohol is a much different chemical than the ethyl alcohol used in alcoholic beverages. Rubbing alcohol is highly toxic and is unfit for human consumption. Isopropyl rubbing alcohol is rubbing alcohol but with isopropyl alcohol instead of ethyl alcohol. Rubbing alcohol is a type of denatured alcohol, but typically contains less ethanol (about 70%) and more additives. This makes denatured alcohol a more sustainable alternative to other cleaning products that are overloaded with chemicals. So, why is denatured alcohol considered to be better for the environment? Denatured alcohol usually consists of mainly ethanol and methanol.Įthanol, or ethyl alcohol, is mainly derived from grains and vegetables, and methanol, or methyl alcohol, used to be produced as a byproduct of wood stock, although nowadays it is often derived from methane in natural gas. Why Is Denatured Alcohol More Eco-Friendly? And denatured alcohol is also considered one of these greener products. If you get 99.9% pure methanol it is a very clean solvent that will leave behind no residue at all and will evaporate quickly.Fortunately, in recent years there has been a rise in eco-friendlier cleaning products, such as vinegar, eucalyptus oil, and baking soda. Wear rubber gloves, use it in a ventilated area, don't get it on your skin and don't breathe the fumes. ![]() However methanol is poisonous so it should be used with care. This you may find from an optics supplier like a camera shop or a telescope shop. For optics, methanol is often chosen as a cleaning fluid. I really wouldn't want to use this as a high purity solvent, but in any case it doesn't dissolve solder flux so it's of little use for cleaning circuit boards. What you find instead is denatured alcohol, which is ethanol mixed with some gasoline and other adulterants to make it undrinkable. In the USA methylated spirits is rarely found. It should be a fairly clean solvent but the dye and bitter substance could be left behind as a residue when it evaporates. Methylated spirits is ethanol mixed with some methanol to make it poisonous, a bitter substance to make it undrinkable, and a purple dye to warn you what it is. Pure anhydrous alcohol >99.9% would also be a clean solvent except you can't obtain it outside of a chemical laboratory and in any case it does not dissolve flux or grease very well. The IPA in my cleaning supplies is >99.9% pure and it should evaporate with no residue. IPA is quite good at cleaning greasy marks, fingerprints, solder flux etc, from glass, circuit boards, tape heads and optics. Methylated spirits is predominantly ethanol, whereas IPA is predominantly isopropyl alcohol. They are different solvents with different dissolving properties. Infused with skincare ingredients to hydrate, protect and perfect the look of your complexion for flawless, poreless looking skin!.This is my NEXT-GENERATION, HIGH-PERFORMANCE foundation with smoothing, pore-blurring, AIRbrush effects!.Visit my Complexion Matrix to discover more flawless matches! I recommend matching this shade with Magic Vanish in 4 Deep, Magic Away Concealer in 15 Dark, Airbrush Flawless Finish in 3 Deep, Genius Magic Powder in 3 Dark, Magic Foundation in 12 Dark, Light Wonder in 10 Dark and Airbrush Bronzer in 4 Deep. Your overtone is what you see in the mirror, and your undertone is determined by the colour of the veins on the underside of your wrist! 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